http://eng.sut.ac.th/polymer/2015/newversion/administrator/document/subjectDocument/14260434504698.pdf WebNov 7, 2006 · Scission theories for laminar flow hypothesize that the drag force, F d, experienced by the chain induces a tension that breaks the molecule if it is greater than the critical strength of a polymer covalent bond.In a purely extensional flow, for example, the maximum tension is at the midpoint ().If the extended chain is modeled as a slender rod, …
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Susceptibility to photo-oxidation varies depending on the chemical structure of the polymer. Some materials have excellent stability, such as fluoropolymers, polyimides, silicones and certain acrylate polymers. However, global polymer production is dominated by a range of commodity plastics which account for the majority of plastic waste. Of these polyethylene terephthalate (PET) has only m… WebChain scission reduces the molecular weight of the macromolecules of a polymer and this finds some commercial applications in problems concerned with molecular weight … edwin neff
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WebAug 14, 1998 · The role of chain scission in the mechanical degradation of polyethylene has been examined using Fourier transform infrared spectroscopy to measure changes … WebChain cross-linking has the opposite effect. An increase in the number of cross-links (due to an oxidative environment for example), results in stronger, less ductile material. The thermal oxidation of polyethylene provides a quality example of chain scission embrittlement. The random chain scission induced a change from ductile to brittle ... WebApr 1, 2012 · The main pathway of degradation is given for each sample. It results in oxidation, chain scission or cross-linking. Cross-linking levels are dependant on the type of ageing, the chemical structure ... contact cra for business